[an error occurred while processing this directive] ������� 2017, 36(3) 862-870,879 DOI:   10.3969/j.issn.1004-5589.2017.03.019  ISSN: 1004-5589 CN: 22-1111/P

����Ŀ¼ | ����Ŀ¼ | ������� | �߼�����                                                            [��ӡ��ҳ]   [�ر�]
��������
��չ����
������Ϣ
Supporting info
PDF(883KB)
[HTMLȫ��]
�����[PDF]
�����
�����뷴��
�ѱ����Ƽ�������
�����ҵ����
�������ù�����
����
Email Alert
���·���
���������Ϣ
���Ĺؼ����������
��Ե
�㿨����
ϡ��Ԫ��
��٪��ͳ
ʯ�Ź���
��ҳ��
������
���������������
���˱�
������
���о�
��ƽ��
������
������
PubMed
Article by Wang K
Article by Meng Q
Article by Liu Z
Article by Sun P
Article by Xu Y
Article by Bai Y
��Ե�㿨������٪��ͳʯ�Ź���ҳ�Ҷ�ϡ��Ԫ�ص���ѧ�������������
���˱�1,2,3, ������1,2,3, ���о�1,2,3, ��ƽ��1,2,3, ������4, ������1,2,3
1. ���ִ�ѧ�����ѧѧԺ, ���� 130061;
2. ����ʡ��ҳ�Ҽ�������Դ����ص�ʵ����, ���� 130061;
3. ��ҳ���빲����Դ����ɿ󼰿��鿪���ص�ʵ����, ���� 130061;
4. �й����ʵ����������Դ��������, ���� 100029
ժҪ�� �Բ��ľ��ر�Ե����Ʋ�Ե���㿨��������ҳ1����YYY-1��ҳ�Ҷ�ϡ��Ԫ�ص���ѧ��������ʾ����ԹŻ���������Դ�͹��������Ӧ����̽���˶���ҳ�ҳɿ��Ӱ�졣�������������ʯ�Ź���ҳ�Ҷ�ϡ��Ԫ����������REE��Ϊ��139.16~342.59��×10-6��ƽ��ֵΪ236.66×10-6�����ڱ���ҳ�ң�NASC���ͺ�̫����ҳ�ң�PASS������LREE/��HREE�ͣ�La/Yb��N�ȵ���ѧ��������������ϡ��Ԫ�ط������ԣ��ֲ�ģʽΪ��ϡ��Ԫ�ظ�������ϡ��Ԫ����Կ��𡣵���ѧ�����Լ�La/Yb-��REEͼ��������о�����Դ��ҪΪ�ϵؿdz����Һͻ�ɽ�ҵĻ����Դ��Ԫ��Eu�������Եĸ��쳣��ָʾ����ˮ��Ϊȱ���Ļ�ԭ������Ϊ��ҳ�����л��ʵĸ����ṩ���õı������������ݸߺ����Ħ�REEֵ�Լ���Eu�쳣ֵ�����ǰ�˶Ըõ������߷��о��ɹ���ʯ�Ź���ҳ�Ҷ��γ���ůʪ������������Ϊ��ҳ�ҵ��γ��ṩ���õ�������Դ�ͱ���������
�ؼ����� ��Ե   �㿨����   ϡ��Ԫ��   ��٪��ͳ   ʯ�Ź���   ��ҳ��   ������  
Rare earth element geochemical characteristics and geological significance of shale member in Middle Jurassic Shimengou Formation in Yuqia area of northern margin of Qaidam Basin
WANG Ke-bing1,2,3, MENG Qing-tao1,2,3, LIU Zhao-jun1,2,3, SUN Ping-chang1,2,3, XU Yin-bo4, BAI Yue-yue1,2,3
1. College of Earth Sciences, Jilin University, Changchun 130061, China;
2. Key Laboratory for Oil Shale and Coexisting Minerals of Jilin Province, Changchun 130061, China;
3. Key Laboratory for Mineralization, Exploration and Exploitation of Oil Shale and Paragenetic Energy Minerals, Changchun 130061, China;
4. Oil & Gas Survey, China Geological Survey, Beijing 100029, China
Abstract: In this paper, the geochemical characteristics of REE from shale member of Shimengou Formation in Well YYY-1 have been analyzed, which illustrated the significance of paleoenvironment, paleoprovenance and paleoclimate, and revealed the impact on oil shale mineralization. The results show that the total content of REE(��REE)of shale member of Shimengou Formation varied from 139.16×10-6 to 342.59×10-6 with an average at 236.66×10-6, which is higher than the content of NASC and PASS. Geochemical parameters such as the ratios of ��LREE/��HREE, (La/Yb)N indicate an obvious differentiation of ��LREE and ��HREE. The REE distribution patterns show that LREE is obviously richer than HREE. Geochemical parameters and La/Yb-��REE diagram suggest that the paleoprovenance was a mixture of sedimentary and volcanic rocks from the upper crust. Eu is obviously negative abnormality, indicating that the sediment was formed in anoxic environment suggesting that anoxic environment is in favour of the organic matter of oil shale enrichment. According to the high levels of ��REE and ��Eu abnormal value, combined with previous research results based on sporopollen, the shale member of Shimengou Formation formed in the warm and humid climate conditions, which provided a good source of material and preservation conditions for the oil shale.
Keywords: northern margin of Qaidam Basin   Yuqia area   rare earth element   Middle Jurassic   Shimengou Formation   oil shale   paleoclimate  
�ո����� 2016-10-26 �޻����� 2016-11-28 ����淢������  
DOI: 10.3969/j.issn.1004-5589.2017.03.019
������Ŀ:

�й����ʵ����������Դ��������ս��ѡ����Ŀ��1211302108025-3-1�����й����ʵ����������Դ�������ĵ��ʵ�����Ŀ��DD20160188-01����������.

ͨѶ����: ������(1984),Ů,��ʿ,������,��Ҫ����ʯ�͵���ѧ������ѧ����ҳ�ҳɿ����۵��о����ѧ.E-mail:mengqt@jlu.edu.cn
���߼��:
����Email: mengqt@jlu.edu.cn

�ο����ף�
[1] ������,���о�,����,��. ������ʼ��ͳ��ҳ��ϡ��Ԫ�ص���ѧ���������������[J]. ���ִ�ѧѧ��:�����ѧ��,2013,34(2):390-399. MENG Qin-tao,LIU Zhao-jun, HU Fei,et al. Geochemical charateristics of Eocene oil shale and its geological significance in Huadian Basin[J]. Journal of Jilin University:Earth Science Edition,2013,34(2):390-399.
[2] Nesbitt H W. Mobility and fractionation of rare earth elements during weathering of a granodiorite[J]. Nature,1979,279:206-210.
[3] ��˶,���о�,��ƽ��,��. ������ض���¡�����ϰ���ͳ�۽�����ҳ�Ҷε���ѧ��������Դ����[J]. �������,2016,35(1):108-122. DENG Shuo,LIU Zhao-jun,SUN Ping-chang,et al. Geochemical characteristics and implications for provenance of shale from Upper Cretaceous Nenjiang Formation of southeast uplifted area in Songliao Basin[J]. Global Geology,2016,35(1):108-122.
[4] ��˷,���о�,��ƽ��,��. ��ɫ���Ҳ�ϵ����ѧ��������Դ����:��������ض���¡�����ϰ���ͳҦ����Ϊ��[J]. �������,2015,34(3):774-785. SONG Shuo,LIU Zhao-jun,SUN Ping-chang,et al. Geochemical characteristics and sediment provenance analysis of red mudstone formation:a case study of Upper Cretaceous Yaojia Formation of southeastern uplift area in Songliao Basin[J]. Global Geology,2015,34(3):774-785.
[5] ��˫��,Ф����,�����,��. ������ǭ������־��ϵϡ��Ԫ�ص���ѧ���������������[J]. �ִ�����,2008,22(2):273-280. LI Shuang-jian,XIAO Kai-hua,WO Yu-jin,et al. REE geochemical charateristics and their geological signification in Silurian West of Hunan Province and North of Guizhou Province[J]. Geoscience,2008,22(2):273-280.
[6] ʷ����,��ѩ��,����,��. �ຣ��QH1����ȫ����������ϡ��Ԫ�ص���ѧ�����򻷾���ϵ̽��[J]. ������ѧ,2003,15(1):28-34. SHI Ji-an,GUO Xue-lian,WANG Qi,et al. Geochemistry of REE in QH1 sediments of Qinghai Lake since Late Holocene and its paleoclimatic significance[J]. Journal of Lake Sciences,2003,15(1):28-34.
[7] ����ϼ,���޸�,̷����,��. Ǽ������ǵ׸��յ�����٪��ͳ-�°���ͳ̼������ϡ��Ԫ�ص���ѧ�������[J]. ����������˹����,2010,30(4):92-96. ZHU Li-xia, FU Xiu-gen,TAN Fu-wen,et al. REE geochemistry of the Upper Jurassic-Lower Cretaceous carbonate rocks and palaeoclimates in the Nadigangri region Qiangtang Basin[J]. Sedimentary Geology and Tethyan Geology,2010, 30(4):92-96.
[8] ���и�,��ѧԪ,����,��.ϡ��Ԫ�ص���ѧ[M]. ����:�Ƽ�������,1989:1-496. WANG Zhong-gang,YU Xue-yuan,ZHAO Zhen-hua,et al. Rare earth element geochemistry[M]. Beijing:Science and Technology Press,1989:1-496.
[9] ����. ΢��Ԫ�ص���ѧԭ��[M]. ����:��ѧ������,1997:15-95. ZHAO Zhen-hua. Trace element geochemical principle[M]. Beijing:Science and Technology Press,1997:15-95.
[10] ���о�,���,����ˮ,��. �й���ҳ��[M]. ����:ʯ�͹�ҵ������,2009:38-116. LIU Zhao-jun,YANG Hu-lin,DONG Qing-shui,et al. Chinese oil shale[M]. Beijing:Petroleum Industry Press,2009:38-116.
[11] ������,������,����,��. ���ľ��ر�Ե��٪��ͳ��ú�����߶���Դ���л�����ѧ����������DZ��[J]. ��У����ѧ��,2007,13(4):703-713. LIU Yun-tian,YANG Shao-yong,HU Kai,et al. Organic geochemical features of mudstone source rock from Member 7 Strata of Middle Jurassic Age in the northern margin of Qaidam Basin and its hydrocarbon-generation potential[J]. Geological Journal of China Universities,2007,13(4):703-713.
[12] �ܽ�,������,������,��. ���ľ��ر�Ե�С���٪��ͳ��Դ������DZ��[J]. �½�ʯ�͵���,2009,30(1):21-24. CAO Jian,BIAN Li-zeng,LIU Yun-tian,et al. Hydrocarbon generative potential of Middle and Lower Jurassic source rocks in northern margin of Qaidam Basin[J].Xinjiang Petroleum Geology,2009,30(1):21-24.
[13] ������,��ƽ,������,��. ���ľ��ر�Ե����٪��ͳ������������ʯ�͵�������[J]. �������ǰ��,2011,27(11):38-44. YUE Peng-sheng,WANG Ping,YU Dong-liang,et al. Depositional characteristics of the Early and Middle Jurassic on the northern margin of the Qaidam Basin and their implications for petroleum geology[J]. Marine Geology Frontiers,2011,27(11):38-44.
[14] ������. ���ľ��ر�Ե��٪��ͳҳ�����ɲ���������:˶ʿѧλ����[D]. ����:������ѧ,2015. WANG Xiao-peng. Shale gas reservoir conditions analysis of Middle Jurassic in the northern Qaidam Basin:master's degree thesis[D]. Xi'an:Chang'an University,2015.
[15] ����. ���ľ��ر�Ե٪��ϵ������ϵ��ҳ������������:��ʿѧλ����[D]. ����:�й���ҵ��ѧ,2014. LI Meng. Sedimentology and shale gas accumulation of the Jurassic in the northern Qaidam Basin:doctor's degree thesis[D]. Beijing:China University of Mining,2014.
[16] ������,����,������,��. ���ľ��ر�Ե٪��ϵҳ����������������������[J]. ��ѧǰԵ,2014,21(4):311-322. SHAO Long-yi,LI Meng,LI Yong-hong,et al. Geochemical charateristics and controlling factors of shale gas in the Jurassic of the northern Qaidam Basin[J]. Earth Science Frontiers,2014,21(4):311-322.
[17] �ܸ���,�����,���,��. ���ľ��ر�Ե���������٪��ͳ���������о�[J]. ���ɹ�ʯ�ͻ���,2005,12:86-90. KOU Fu-de,ZHU Yu-jie,LI Jian-ming,et al. Reservoir characteristics of the Lower Jurassic on Lenghu area of the margin of Qaidam Basin[J]. Inner Mongolia Petrochemical Industry,2005,12:86-90.
[18] ������,�º���,���,��. ��Ե�㿨��ú�����߶���ҳ�ҿ�����ֵ[J]. ����ʯ�ʹ�ѧѧ��:��Ȼ��ѧ��,2013,35(3):52-58. Ma Xin-min,HAO Hai-yan,MA Feng,et al. Developmental value of oil shale in the 7th member of Middle Jurassic in Yuqia area, Qaidam Basin[J]. Journal of Southwest Petroleum University:Science & Technology Edition,2013,35(3):52-58.
[19] ³��,������,���켨,��. ��Ե�㿨����٪�޼ͺ�ú�ز����ز�ѧ�о�[J]. ú������뿱̽,2007,35(1):1-6. LU Jing,SHAO Long-yi,LIU Tian-ji,et al. A sequence stratigraphic analysis of the Jurassic coal measures in Yuqia region of northern Qaidam Basin[J]. Coal Geology & Exploration,2007,35(1):1-6.
[20] ��ƺ�,������,������,��. ���ľ����㿨����٪��ϵ��ҳ�ҵ���ѧ��������������:�Բ�ҳ1��Ϊ��[J]. ����ͨ��,2016,35(����1):250-259. LI Hao-han,REN Shou-mai,GUO Tian-xu,et al. Organic geochemistry characteristics and reservoir conditions of Jurassic shale in Yuqia depression of northern Qaidam Basin:a case study of Chaiye-1 Well[J]. Geological Bulletin of China,2016,35(Suppl.1):250-259.
[21] ������,�����,������,��. ���ľ����㿨������٪��ͳҳ�����ɲ�����[J]. ����ͨ��,2016,35(����1):231-241. WANG Xiao-peng,LI Yu-hong,ZHANG Yun-peng,et al. An analysis of reservoir forming conditions of shale gas in Middle Jurassic strata of Yuqia area,Qaidam Basin[J]. Geological Bulletin of China,2016,35(Suppl.1):231-241.
[22] Taylor S R,McLennan S M. The continental crust:its composition and evolution[M]. Oxford:Blackwell,1985:12-312.
[23] Murray R W,Buchholtz M R,Jones D L.Rare earth elements as indicators of different marine depositional environment in chert and shale[J]. Geology,1990,18(3):268-271.
[24] �̹�ǿ,����,����̫,��. մ�������½�ϵ�����ҵ���ѧ����������Դָʾ����[J]. ���ʿƼ��鱨,2007,26(6):17-24. CAI Guan-qiang,GUO Feng,LIU Xian-tai,et al. Geochemical characteristics of Neogene sedimentary rocks from Zhanhua Sag and its implication for provenance[J]. Geological Science and Technology Information,2007,26(6):17-24.
[25] Allegre C J,Minster J F. Quantitative models of trace element behavior in magmatic processes[J]. Earth and Planetary Science Letters,1978,38(1):1-25.
[26] ����. ijЩ����ϡ��Ԫ�ص���ѧ�����ļ��㷽���������ѧ����[J]. ���ʵ���ѧ,1985,(����1):11-14. ZHAO Zhen-hua. Some methods of calculation of geochemical parameters of rare earth elements and the geochemical significance[J]. Geology-Geochemistry,1985,(Suppl.1):11-14.
[27] Elderfield H,Greaves M J. The rare earth elements in seawater[J]. Nature,1982,296(18):214-219.
[28] ����,���о�,��Ρ,��. �͸�ë����ҳ����ϡ��Ԫ�������о������������[J]. ����ѧ,2010,39(4):364-370. LIU Rong,LIU Zhao-jun,GUO Wei, et al. Rare earth element characteristics of Bagemaode oil shale Inner Mongolia China[J]. Geochimica,2010,39(4):364-370.
[29] ����,������,ׯ��,��. ��ˮ��عŽ�ϵ�²����������ϡ��Ԫ�ص���ѧ�����������������[J]. ����ѧ��,2009,27(6):1155-1162. CHEN Liang,LIU Chun-lian,ZHUANG Chang,et al. Rear earth element records of the Lower Paleogene sediments in the Sanshui Basin and their paleoclimate implications[J]. Acta Sedimentologica Sinica,2009,27(6):1155-1162.
[30] ������,������.�������������ͺ���ϡ��Ԫ�صij����о�[J]. �����������ļ͵���,2000,20(2):39-43. PENG Shu-zhen,GUO Zheng-tang. A preliminary study on REE of the Late Tertiary laterite in Xifeng Area[J]. Marine Geology & Quaternary Geology,2000,20(2):39-43.
[31] ���庣,������,���,��. ����ƽԭ������߷۳������о�[J]. �ŵ���ѧ��,2001,3(2):55-63. XU Qing-hai,LI Run-lan,ZHU Feng,et al. Pollen sedimentary facies of fluvial sediments on North China Plain[J]. Journal of Palaeogeography,2001,3(2):55-63.
[32] ������. �Ϻ���������ȫ�����߷���ϼ���ֲ���͹�����[J]. �ŵ���ѧ��,2006,8(1):35-41. ZHANG Yu-lan. Palynological assemblage and palaeovegetation and palaeoclimate of the Holocene in eastern Shanghai[J]. Journal of Palaeogeography,2006,8(1):35-41.
[33] ��ƽ,л�ڿ�,Ԭ���,��. ���ľ��ر�Ե٪�޼͹���̬��������ŵ�������[J]. �ŵ���ѧ��,2006,8(2):165-173. YANG Ping, XIE Zong-kui, YUAN Xiu-jun,et al. Palaeoecological characteristics and its palaeogeographic significance of the Jurassic in northern margin of Qaidam Basin[J]. Journal of Palaeogeography,2006,8(2):165-173.
[34] �����,�����. ���ľ���٪��ϵ��Դ���߷�ѧ֤��[J]. ֲ��ѧ��,1997,39(12):1160-1164. JIANG De-xin,YANG Hui-qiu. Palynological evidence for Jurassic petroleum source of Qaidam Basin[J]. Acta Botanica Sinica,1997,39(12):1160-1164.
�������������
1������, ���о�, ��ƽ��, ������, ��˷.���ľ����㿨������٪��ͳʯ�Ź���ɰ����м�������������Դ���컷������[J]. �������, 2018,37(1): 154-161
2���촨, ������, ���о�, ��ƽ��, ���, ������.��Ե�㿨������٪��ͳʯ�Ź�����ҳ��Ʒ����������������ǰ��[J]. �������, 2017,36(3): 871-879
3������, ����, �����, ����, ������, �����.��Եţ���������������������ʯU-Pb���ѧ������ѧ�о�[J]. �������, 2017,36(1): 93-104
4���ܿ�, ���Ѻ�, ��ǿ, ����, ��ʿ��, ���.ũ����ҳ�����ؼ����������������о�[J]. �������, 2016,35(4): 1178-1184
5��л��Ȫ, ���о�, ����, ������, ��˶, ��˷, �ų�.������ض���¡�������� 3 ���ϰ���ͳ��ɽ������ҳ������[J]. �������, 2016,35(3): 850-857
6��������, ���о�, ����, л��Ȫ, ��˷.������ط���—����������ϰ���ͳ��ɽ������ҳ��Ʒ������������[J]. �������, 2016,35(2): 487-494
7����˶, ���о�, ��ƽ��.������ض���¡�����ϰ���ͳ�۽�����ҳ�Ҷε���ѧ��������Դ����[J]. �������, 2016,35(1): 108-122
8��������, ֣����, ���о�, ����, ��ƽ��, ���˽�.������ʼ�����߷��������������ָʾ����[J]. �������, 2016,35(1): 1-8
9�����, ����, ������, �����.��ҳ�ҵ��¸���ͬ�׶εIJ�������[J]. �������, 2015,34(3): 870-878
10�����, Ҧ����, ��ƽ��, ������, ����, ������.÷�������ҳ������������[J]. �������, 2014,33(2): 457-464
11������, ����Ӣ, ���, ����ɽ.������ҳ����Դ����������״�뷢չǰ��[J]. �������, 2012,31(4): 772-777
12�����, ������, ������, ��ƽ��,.���ݺ�������ظ��л������Ҳ��Բ������о�����[J]. �������, 2012,31(4): 778-784
13��������, ����, ���о�, ������, ��ƽ��, ��С��, ������.���ӹ���ش���������ҳ���л�����ѧ���������������[J]. �������, 2012,31(2): 315-412
14������, ������, ���·�, ����, ��԰԰.�����ӱߵ�������ϡ��Ԫ�صĻ��������Ӱ������[J]. �������, 2012,31(1): 224-230
15������ƽ, ����,.��ͬ���������Ҷ���ʲ�΢�������仯�������������[J]. �������, 2010,29(4): 543-547

Copyright by �������