In order to improve the properties of HDPE, the authors used the method of suspended diffusion for purification the pelagic clay, used silane coupling agent to increase its organic activation, and prepared the composites of organic pelagic clay/HDPE bymelting them in different conditions. The affections of process conditions and quantity of pelagic clay to the properties of composites were analyzed by testing their mechanical properties, thermo stability and barrier properties. According to test the structure of composites, it is indicated that pelagic clay has good compatibility with HDPE. The result shows that the pelagic clay can improve mechanical properties, thermo stability and barrier properties of HDPE properties effectively.