[an error occurred while processing this directive] 世界地质 2019, 38(4) 999-1011 DOI:   10.3969/j.issn.1004-5589.2019.04.011  ISSN: 1004-5589 CN: 22-1111/P

本期目录 | 下期目录 | 过刊浏览 | 高级检索                                                            [打印本页]   [关闭]
油气地质
扩展功能
本文信息
Supporting info
PDF(3211KB)
[HTML全文]
参考文献[PDF]
参考文献
服务与反馈
把本文推荐给朋友
加入我的书架
加入引用管理器
引用本文
Email Alert
文章反馈
浏览反馈信息
本文关键词相关文章
有机质孔隙
有机黏土复合体
页岩气储层
下寒武统
上扬子地区
本文作者相关文章
刘忠宝
边瑞康
高波
王鹏威
王濡岳
金治光
杜伟
PubMed
Article by Liu Z
Article by Bian R
Article by Gao B
Article by Wang P
Article by Wang R
Article by Jin Z
Article by Du W
上扬子地区下寒武统页岩有机质孔隙类型及发育特征
刘忠宝1,2, 边瑞康2, 高波2, 王鹏威2, 王濡岳2, 金治光3, 杜伟2
1. 页岩油气富集机理与有效开发国家重点实验室, 北京 100083;
2. 中国石油化工股份有限公司 石油勘探开发研究院, 北京 100083;
3. 中国石油大学(北京)地球科学学院, 北京 102249
摘要: 为揭示古老层系过成熟页岩有机质孔隙的发育特征,以上扬子地区下寒武统页岩为例,采用岩石薄片、有机岩石学、有机地球化学、氩离子抛光-扫描电镜等多种技术方法,重点从有机质组成及有机质的赋存方式的角度,开展了有机质孔隙类型的识别,分析了各类孔隙的发育特征及形成机制。研究结果表明:下寒武统页岩主要发育3种有机质孔隙类型:固体沥青内有机质孔隙、有机质-无机矿物复合体内有机质孔隙及莓状黄铁矿集合体内有机质孔隙;页岩固体沥青内有机质孔隙普遍较发育,但孔径小(<30 nm),页岩中天然气大量散失是导致有机质孔隙坍塌萎缩变小的主要原因;有机黏土复合体和莓状黄铁矿集合体形成的稳定抗压结构,有利于有机质孔隙及页岩气的保存。
关键词 有机质孔隙   有机黏土复合体   页岩气储层   下寒武统   上扬子地区  
Organic matter pore types and development characteristics of Lower Cambrian shale in Upper Yangtze area
LIU Zhong-bao1,2, BIAN Rui-kang2, GAO Bo2, WANG Peng-wei2, WANG Ru-yue2, JIN Zhi-guang3, DU Wei2
1. State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development, Beijing 100083, China;
2. Petroleum Exploration and Production Research Institute, SINOPEC, Beijing 100083, China;
3. College of Geosciences, China University of Petroleum(Beijing), Beijing 102249, China
Abstract: To reveal the organic matter pore development characteristics of the over-mature shale in the old strata, organic matter pores identification, development characteristics and forming mechanism of pores of Lower Cambrian shale in Upper Yangtze area were studied based on organic components and occurrence manner through thin-sections, organic petrology, organic geochemistry and Ar ion milling/SEM technologies. Results show that or-ganic matter pores in the Lower Cambrian shale consist of three types, i. e., organic matter pores in the solid bitu-men, in the organic matter-inorganic mineral complex and in the strawberry pyrite assemblage. Organic matter pores in the solid bitumen widely occurred but with small pore diameter (<30 nm), and the expulsion of massive gas was responsible for the collapse and shrinkage of organic matter pores. Organic matter-clay complex and straw-berry pyrite assemblage can form stable anti-compression structures, which are favorable for the preservation of or-ganic matter pores and shale gas in them.
Keywords: organic matter pores   organic matter-clay complex   Lower Cambrian   Upper Yangtze area  
收稿日期 2019-06-12 修回日期 2019-10-10 网络版发布日期  
DOI: 10.3969/j.issn.1004-5589.2019.04.011
基金项目:

国家自然科学基金项目(41872124)、中国石化科技部项目(P15114)与国家科技重大专项(2017ZX05036002001)联合资助。

通讯作者:
作者简介:
作者Email:

参考文献:
[1] 聂海宽, 张金川, 李玉喜. 四川盆地及其周缘下寒武统页岩气聚集条件[J]. 石油学报, 2011, 32(6):959-967. NIE Hai-kuan, ZHANG Jin-chuan, LI Yu-xi. Accumula-tion conditions of the Lower Cambrian shale gas in the Si-chuan Basin and its periphery[J]. Acta Petrolei Sinica, 2011, 32(6):959-967.
[2] 聂海宽, 唐玄, 边瑞康. 页岩气成藏控制因素及我国南方页岩气发育有利区预测[J]. 石油学报, 2009, 30(4):484-491. NIE Hai-kuan, TANG Xuan, BIAN Rui-kang. Control-ling factors for shale gas accumulation and prediction of potential development area in shale gas reservoir of South China[J]. Acta Petrolei Sinica, 2009, 30(4):484-491.
[3] 程克明, 王世谦, 董大忠, 等. 上扬子区下寒武统筇竹寺组页岩气成藏条件[J]. 天然气工业, 2009, 29(5):40-44. CHENG Ke-ming, WANG Shi-qian, DONG Da-zhong, et al. Accumulation conditions of shale gas reservoirs in the Lower Cambrian Qiongzhusi Formation, the Upper Yan-gtze region[J]. Natural Gas Industry, 2009, 29(5):40-44.
[4] 黄金亮, 邹才能, 李建忠, 等. 川南下寒武统筇竹寺组页岩气形成条件及资源潜力[J]. 石油勘探与开发, 2012, 39(1):69-75. HUANG Jin-liang, ZOU Cai-neng, LI Jian-zhong, et al. Shale gas generation and potential of the Lower Cambrian Qiongzhusi Formation in southern Sichuan Basin, China[J]. Petroleum Exploration and Development, 2012, 39(1):69-75.
[5] Chalmers G R, Bustin R M, Power I M. Characterization of gas shale pore systems by porosimetry, pycnometry, surface area, and field emission scanning electron micros-copy/transmission electron microscopy image analyses:examples from the Barnett, Woodford, Haynesville, Mar-cellus, and Doig units[J]. AAPG Bulletin, 2012, 96:1099-1119.
[6] Loucks R G, Reed R M, Ruppel S C, et al. Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores[J]. AAPG Bulletin, 2012, 96(6):1071-1098.
[7] Nie H K, Zhang J C, Jiang S L. Types and characteris-tics of the Lower Silurian shale gas reservoirs in and around the Sichuan Basin[J]. Acta Geologica Sinica, 2015, 89(6):1973-1985.
[8] Pommer M, Milliken K. Pore types and pore-size distri-butions across thermal maturity, Eagle Ford Formation, southern Texas[J]. AAPG Bulletin, 2015, 99(9):1713-1744.
[9] 魏秀丽, 冯志鹏, 贺定长, 等. 北美地区页岩储层特征分析[J]. 四川地质学报, 2013, 33(4):435-439. WEI Xiu-li, FENG Zhi-peng, HE Ding-chang, et al. On shale reservoir in the northern America[J]. Acta Geo-logica Sichuan, 2013, 33(4):435-439.
[10] Jarvie D M, Hill R J, Ruble T E, et al. Unconventional shale-gas systems:the Mississippian Barnett shale of north-central Texas as one model for thermogenic shale-gas assessment[J]. AAPG Bulletin, 2007, 91(4):475-499.
[11] 胡宗全, 杜伟, 彭勇民, 等. 页岩微观孔隙特征及源-储关系:以川东南地区五峰组-龙马溪组为例[J]. 石油与天然气地质, 2015, 36(6):1001-1008. HU Zong-quan, DU Wei, PENG Yong-min, et al. Mi-croscopic pore characteristics and the source-reservoir relationship of shale:an example from the Wufeng For-mation and Longmaxi Formation in Southeast Sichuan Basin[J]. Oil & Gas Geology, 2015, 36(6):1001-1008.
[12] 郭旭升, 胡东风, 李宇平, 等. 涪陵页岩气田富集高产主控地质因素[J]. 石油勘探与开发, 2017, 44(4):481-491. GUO Xu-sheng, HU Dong-feng, LI Yu-ping, et al. Ge-ological factors controlling shale gas enrichment and high production in Fuling shale gas field[J]. Petroleum Ex-ploration and Development. 2017, 44(4):481-491.
[13] 何治亮, 胡宗全, 聂海宽, 等. 四川盆地五峰组-龙马溪组页岩气富集特征与"建造-改造"评价思路[J]. 天然气地球科学, 2017, 28(5):724-733. HE Zhi-liang, HU Zong-quan, NIE Hai-kuan, et al. Characterization of shale gas enrichment in the Wufeng-Longmaxi Formation in the Sichuan Basin and its evalua-tion of geological construction-transformation evolution sequence[J]. Natural Gas Geoscience, 2017, 28(5):724-733.
[14] 刘祖发, 谭圣林, 徐良伟, 等. 扬子地区某些下古生界页岩孔隙特征及影响因素[J]. 煤炭学报, 2013, 38(5):783-786. LIU Zu-fa, TAN Sheng-lin, XU Liang-wei, et al. Pore characteristics and their controlled factors of some Lower Paleozoic shales from the Yangtze area[J]. Journal of China Coal Society, 2013, 38(5):783-786.
[15] 罗超. 上扬子地区下寒武统牛蹄塘组页岩特征研究:博士学位论文[D]. 成都:成都理工大学, 2014. LUO Chao. Geological characteristics of gas shale in the Lower Cambrian Niutitang Formation of the Upper Yan-gtze platform:doctor's degree thesis[D]. Chengdu:Chengdu University of Technology, 2014.
[16] 于炳松. 页岩气储层的特殊性及其评价思路和内容[J]. 地学前缘, 2012, 19(3):252-258. YU Bing-song. Particularity of shale gas reservoir and its evaluation[J]. Earth Science Frontiers, 2012, 19(3):252-258.
[17] 郭旭升, 胡东风, 文治东, 等. 四川盆地及周缘下古生界海相页岩气富集高产主控因素:以焦石坝地区五峰组-龙马溪组为例[J]. 中国地质, 2014, 41(3):893-901. GUO Xu-sheng, HU Dong-feng, WEN Zhi-dong, et al. Major factors controlling the accumulation and high pro-ductivity in marine shale gas in the Lower Paleozoic of Sichuan Basin and its periphery:a case study of the Wufeng-Longmaxi Formation of Jiaoshiba area[J]. Geology in China, 2014, 41(3):893-901.
[18] 王淑芳, 张子亚, 董大忠, 等. 四川盆地下寒武统筇竹寺组页岩孔隙特征及物性变差机制探讨[J]. 天然气地球科学, 2016, 27(9):1619-1628. WANG Shu-fang, ZHANG Zi-ya, DONG Da-zhong, et al. Microscopic pore structure and reasons making reser-voir property weaker of Lower Cambrian Qiongzhusi shale, Sichuan Basin, China[J]. Natural Gas Geosci-ence, 2016, 27(9):1619-1628.
[19] 王道富, 王玉满, 董大忠, 等. 川南下寒武统筇竹寺组页岩储集空间定量表征[J]. 天然气工业, 2013, 33(7):1-10. WANG Dao-fu, WANG Yu-man, DONG Da-zhong, et al. Quantitative characterization of reservoir space in the Lower Cambrian Qiongzhusi shale, southern Sichuan Basin[J]. Natural Gas Industry, 2013, 33(7):1-10.
[20] 刘忠宝, 高波, 武清钊, 等. 页岩有机-无机复合型孔隙及其控气作用:以川西南地区筇竹寺组为例[J]. 海相油气地质, 2018, 23(4):42-50. LIU Zhong-bao, GAO Bo, WU Qing-zhao, et al. Organ-ic-inorganic compound pore system and its gas-control-ling significance:a case study of the Cambrian Qiong-zhusi Formation in southwestern Sichuan Basin[J]. Marine Origin Petroleum Geology, 2018, 23(4):42-50.
[21] 刘忠宝, 高波, 胡宗全, 等. 高演化富有机质页岩储层特征及孔隙形成演化:以黔南地区下寒武统九门冲组为例[J]. 石油学报, 2017, 38(12):1381-1389. LIU Zhong-bao, GAO Bo, HU Zong-quan, et al. Res-ervoir characteristics and pores formation and evolution of high maturated organic rich shale:a case study of Lower Cambrian Jiumenchong Formation, southern Guizhou area[J]. Acta Petrolei Sinica, 2017, 38(12):1381-1389.
[22] 刘忠宝, 高波, 张钰莹, 等. 上扬子地区下寒武统页岩沉积相类型及分布特征[J]. 石油勘探与开发, 2017, 44(1):21-31. LIU Zhong-bao, GAO Bo, ZHANG Yu-ying, et al. Types and distribution of the shale sedimentary facies of the Lower Cambrian in Upper Yangtze area, South China[J]. Petroleum Exploration and Development, 2017, 44(1):21-31.
[23] 胡宗全, 杜伟, 刘忠宝. 页岩气源储耦合机理及其应用[M]. 北京:地质出版社, 2018:39. HU Zong-quan, DU Wei, LIU Zhong-bao. Coupling mechanism of shale gas source and reservoir and its ap-plication[M]. Beijing:Geological Publishing House, 2018:39.
[24] 王羽, 金婵, 汪丽华, 等. 应用氩离子抛光-扫描电镜方法研究四川九老洞组页岩微观孔隙特征[J]. 岩矿测试, 2015, 34(3):278-285. WANG Yu, JIN Chan, WANG Li-hua, et al. Charac-terization of pore structures of Jiulaodong Formation shale in the Sichuan Basin by SEM with Ar-ion milling[J]. Rock and Mineral Analysis, 2015, 34(3):278-285.
[25] 刘忠宝, 高波, 冯动军, 等. 上扬子地区下寒武统黑色页岩矿物组成特征及其油气勘探意义[J]. 天然气工业, 2017, 37(4):21-26. LIU Zhong-bao, GAO Bo, FENG Dong-jun, et al. Min-eral composition of the Lower Cambrian black shale in the Upper Yangtze region and its significance in oil and gas exploration[J]. Natural Gas Industry, 2017, 37(4):21-26.
[26] 焦淑静, 张慧, 薛东川, 等. 泥页岩有机显微组分的扫描电镜形貌特征及识别方法[J]. 电子显微学报, 2018, 37(2):137-144. JIAO Shu-jing, ZHANG Hui, XUE Dong-chuan, et al. Morphological structure and identify method of organic macerals of shale with SEM[J]. Journal of Chinese Electron Microscopy Society, 2018, 37(2):137-144.
[27] 王濡岳, 丁文龙, 龚大建, 等. 黔北地区海相页岩气保存条件:以贵州岑巩区块下寒武统牛蹄塘组为例[J]. 石油与天然气地质, 2016, 37(1):45-55. WANG Ru-yue, DING Wen-long, GONG Da-jian, et al. Gas preservation conditions of marine shale in north-ern Guizhou area a case study of the Lower Cambrian Niutitang Formation in the Cen'gong block, Guizhou Province[J]. Oil & Gas Geology, 2016, 37(1):45-55.
[28] 王爱萍, 杨守业, 李从先. 三种沉积环境中有机黏土复合体特征比较[J]. 同济大学学报(自然科学版), 2005, 33(6):785-788, 827. WANG Ai-ping, YANG Shou-ye, LI Cong-xian. Com-parison of organo-clay complex in three sedimentary en-vironments[J]. Journal of Tongji University (Natural Science), 2005, 33(6):785-788, 827.
[29] 蔡进功, 包于进, 杨守业, 等. 泥质沉积物和泥岩中有机质的赋存形式与富集机制[J]. 中国科学(D辑), 2007, 37(2):234-243. CAI Jin-gong, BAO Yu-jin, YANG Shou-ye, et al. Re-search on preservation and enrichment mechanisms of or-ganic matter in muddy sediment and mudstone[J]. Science in China (Ser. D), 2007, 37(2):234-243.
[30] 王行信, 万玉兰. 有机黏土复合体在石油生成中的意义[J]. 中国海上油气(地质), 1993, 7(2):27-33. WANG Xing-xin, WAN Yu-lan. Significance of the or-ganic clay polymer on oil and gas generation[J]. Chi-na Offshore oil and Gas (Geology), 1993, 7(2):27-33.
本刊中的类似文章
1.陈海潮, 王璞珺, 衣健, 武成智, 王寒非, 孙松, 王文华.长白山火山碎屑喷出物和熔岩地球化学特征及其对构造环境的指示意义[J]. 世界地质, 2020,39(2): 294-305
2.蒋立伟, 刘永江, 冯志强, 汤超.大兴安岭北段裸河组物源及其构造环境:来自地球化学和碎屑锆石年代学的证据[J]. 世界地质, 2018,37(3): 688-701
3.朱欣然, 刘立, 贾士琚, 李睿祺, 宫昀迪.鄂尔多斯盆地白垩系洛河组风成砂岩地球化学与物源区特征:以靖边县龙洲乡露头为例[J]. 世界地质, 2018,37(3): 702-711
4.王涛, 刘招君, 孙平昌, 白悦悦, 宋朔.柴达木盆地鱼卡地区中侏罗统石门沟组砂岩碎屑组分特征及其物源构造环境分析[J]. 世界地质, 2018,37(1): 154-161

Copyright by 世界地质