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2022, 41(4) 703-723 DOI:
ISSN: 1004-5589 CN: 22-1111/P |
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Geochronology,geochemistry and tectonic significance of Early Cenozoic volcanic rocks in Huizhou sag of Pearl River Mouth Basin |
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XUAN Changji1,2,LI Xiaoping1,2,WANG Fei1,2,XIE Shiwen1,2,ZHOU Fengjuan1,2 |
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1. Shenzhen Branch of CNOOC Ltd.,Shenzhen 518000,Guangdong,China;
2. CNOOC Deepwater Development Ltd.,Shenzhen 518000,Guangdong,China
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Abstract:
In this paper,the authors present a systematic study of the petrology,zircon U--Pb geochronology
and geochemistry of the Early Cenozoic volcanic rocks exposed by drilling in the Huizhou sag of the Pearl River Mouth Basin ( PRMB) ,in order to explore their petrogenesis and tectonic environment. Petrological and geochemical analyses show that the studied volcanic rocks are composed of andesite,dacite and trachyandesite. LA--ICP--MS zircon U--Pb geochronology reveals that the crystallization age of the volcanic rocks are ( 60. 8 ± 1. 0) ~ ( 56. 7 ±1. 7) Ma,i. e.,the age is Paleocene. The studied rocks have w ( SiO2 ) of 57. 59% ~ 66. 63% ,w ( Na2O + K2O) of 3. 98% ~ 9. 85% ,w ( Al2O3 ) of 16. 93% ~ 20. 50% ,w ( MgO) of 1. 37% ~ 3. 12% ,w ( TiO2 ) of 0. 49% ~0. 74% ,w ( TFe2O3 ) of 3. 77% ~ 6. 78% ,and Mg# value of 21. 98 ~ 28. 30. These rocks belong to calc-alkaline,high-K calc-alkaline,shoshonite and qusi-aluminous series. The rocks exhibit enrichments in LREE with the LREE /HREE ratios of 7. 88 ~ 10. 16 and ( La /Yb) N ratios of 9. 64 ~ 11. 92 ( 11. 08 on average) ,and show slight negative Eu anomalies with δEu values of 0. 70 ~ 1. 01 ( 0. 88 on average) . These samples are relatively enriched in LILEs such as Ba and K,and depleted in HFSEs such as Nb,Ta and Ti. Petrogenesis analysis shows that the Paleocene intermediate-acid volcanic rocks originated from the mafic lower crust in high pressure conditions,and they are the partial melting products under garnet or amphibolite facies. Combined with regional data,we propose that the PRMB was in a volcanic arc enviroment related to the subduction of the Paleo--Pacific slab beneath the South China block in the Paleocene. |
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Keywords:
geochronology
geochemistry
volcanic rocks
Paleocene
Huizhou sag
Pearl River Mouth Basin
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Received Revised Online: |
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