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Geochemical characteristics and its paleo-environmental significance of Permian carbonate rocks in Khorat Basin, Thailand
DU Gui-chao, CANG Hui, HU Shuang-quan, CAO Qing-rong, GAO Peng-peng
Institute of Shaanxi Yanchang Petroleum(Group) Corporation, Xi'an, 710075, China
Abstract:

Based on testing methods of ICP-AES and stable isotope mass spectrometry, the authors we analyzed the compositions of trace elements, carbon and oxygen isotopes of Permian carbonate rocks in Khorat Basin. Studies were also carried out on the palaeo-sedimentary environment and its significance for the development of carbonate source rocks in the studied area. The comprehensive examination of δ13C/δ18O, Sr/Ba, V/Ni, V/(V+Ni) results show that sedimentary environment in shallower slope sub-facies of the studied area is typically characterized by fresh-brackish water and weak oxidation-weak reduction environment. Deeper slope sub-facies located below the wave base is characterized by brackish-saline water, anoxic and reduction environment, which is favorable for the preservation of organic matter. Deeper slope sub-facies are confirmed to be more favorable for the development of carbonate source rocks in the studied area.

Keywords: Khorat Basin   Permian carbonate rocks   sedimentary environment   trace element   carbon and oxygen isotope  
�ո����� 2016-04-19 �޻����� 2016-07-11 ����淢������  
DOI: 10.3969/j.issn.1004-5589.2017.01.011
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[1] �˺���,Ǯ��.��������ѧ�뻷������[M].����:�����ѧ����������,1993:95-104. DENG Hong-wen, QIAN Kai. Sedimentary geochemistry and environmental analysis[M]. Lanzhou:Gansu science and technology press, 1993:95-104.
[2] ����.΢��Ԫ�ص���ѧԭ��[M].����:��ѧ������,1997:183-204. ZHAO Zhen-hua. Principle of trace element geochemistry[M]. Beijing:Science Press, 1997:183-204.
[3] ����ˮ.��Ӫ������б��ɳ�Ķγ��������ĵ���ѧ����[J].������ʯ,2005(1):67-73. SONG Ming-shui. Sedimentary environment geochemistry in the Shasi section of southern ramp, Dongying depression[J]. Journal of Mineralogy and Petrology, 2005(1):67-73.
[4] ����Ƽ,������,�ﴺ��,��.��������������ݺ���̼��������Դ�ҳ���������Ԫ�ص���ѧ��־[J].������ʯ����ѧͨ��,2013,32(4):456-462. MA Su-ping, XIA Yan-qing, TIAN Chun-tao, et al. Elemental geochemical indicators for sedimentary environment in lacustrine carbonate source rocks of the Biyang depression, Nanxiang basin[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2013, 32(4):456-462.
[5] �����,��֮��.���纬�������ͼ��[M],����:ʯ�͹�ҵ������, 2005:78-79. LI Guo-yu, JIN Zhi-jun. Atlas of the world's oil and gas basin[M].Beijing:Petroleum Industry Press, 2005:78-79.
[6] Metcalfe I. Permian tectonic framework and palaeogeography of SE Asia[J]. Journal of Asian Earth Sciences, 2002(20):551-566.
[7] Ferrari O M, Hochard C, Stampfli G M. An alternative plate tectonic model for the Palaeozoic-Early Mesozoic Palaeotethyan evolution of Southeast Asia (Northern Thailand-Burma)[J]. Tectonophysics, 2008, 451:346-365.
[8] Mohamed E T,Cherdsak U A. Evolution of a Permian carbonate platform to siliciclastic basin:Indochina Plate, Thailand[J]. Sedimentary Geology, 1998, 121:97-119.
[9] ɣ��ѫ,֣����,�Ż�,��.���ݵ����¹�����̼�����ҵ�̼.��ͬλ���о�[J].��ʯѧ��,2003,20(3):707-716. SANG Shu-xun, ZHENG Yong-fei, ZHANG Hua, et al. Researches on carbon and oxygen stable isotopes of lower Paleozoic carbonates in Xuzhou area[J]. Acta Petrologica Sinica, 2003, 20(3):707-716.
[10] Ҧ����,����,������,��. �½������յ����纮����̼�����ҳ�������:΢��Ԫ�غ�̼ͬλ��֤��[J].����ѧ,2011,40(1):63-71. YAO Chun-yan, MA Dong-sheng, DING Hai-feng, et al. Reconstruction of the Early Cambrian carbonate sedimentary environment in Akesu area of Xinjiang, China:evidences from trace elements and carbon isotope excursion[J]. Geochimica, 2011,40(1):63-71.
[11] ������,��ѩ��,������,��. ������͵�����Ӱ������ҵ�̼����ͬλ�غ�΢��Ԫ��ָʾ:���Ͽ�����ĩ��dz����������ԭ����[J].�й���ѧ:�����ѧ, 2015,45:963-981. CHEN Ya-li, CHU Xue-lei, ZHANG Xing-liang, et al. Carbon isotopes, sulfur isotopes and trace elements of the dolomites from the Dengying Formation in Zhenba area, Southern Shaanxi:implications for shallow water redox conditions during the terminal Ediacaran[J]. Science China:Earth Sciences, 2015, 45:963-981.
[12] Veizer J, Ala D, Azmy K, et al. 87Sr/86Sr, δ13C and δ18O evolution of Phanerozoic seawater[J]. Chemical Geology, 1999, 161:59-88.
[13] O'Neil J R, Clayton R N, Mayeda T K. Oxygen isotope fractionation in divalent metal carbonates[J]. Journal of Chemical Physics, 1969, 51:5547-5548.
[14] Kaufman A J, Knoll A H. Neoproterozoic variations in the C-isotopic composition of seawater:stratigraphic and biogeochemical implications[J]. Precabrian Research,1995, 73(1/4):27-49.
[15] Kaufman A J, Jacobsen S B, Knoll A H. The Vendian record of Sr and C isotopic variations in seawater:implications for tectonics and paleoclimate[J]. Earth and Planetary Science Letters, 1993, 120(3/4):409-430.
[16] Jacobsen S B, Kaufman A J. The Sr, C and O isotopic evolution of Neoproterozoic seawater[J]. Chemical Geology, 1999, 161:37-57.
[17] Walker C T. Evaluation of boron as a Palaeosalinity indicator and its application offshore prospects[J]. AAPG Bulletin, 1968, 52(5):751-766.
[18] �����,������,�׽���,��.�������ݺ���԰��΢��Ԫ���ݻ������������������[J].����ѧ��,1997,15(1):66-71. WANG Sui-ji, HUANG Xing-zhen, TUO Jin-cai, et al. Evolutional characteristics and their Paleoclimate significance of trace elements in the Hetaoyuan Formation, Biyang depression[J]. Acta Sedimentologica Sinica,1997, 15(1):66-71.
[19] ����Զ.̼�����ҳ�����ͳ�������[M].����:�й����ʴ�ѧ������,1989:35-43. JIA Zhen-yuan. Carbonate sedimentary facies and sedimentary environment[M]. Beijing:China university of geosciences press, 1989:35-43.
[20] ������,�����.̼��������̼ͬλ�ص���ѧ�о�Ŀǰ���ٵļ�������[J].�����ѧ��չ, 1999,14(3):262-268. LI Xin-qing, WAN Guo-jiang. Problems in studies on carbon and oxygen stable isotopes in carbonates[J]. Advance in Earth Sciences, 1999,14(3):262-268.
[21] �ӽ���,����,���.������˹��ض���Ե��8�Ͳ���̼���ν�����������[J].����������,2011,23(4):65-69. ZHONG Jin-yin, HE Miao, ZHOU Tao. Origin analysis of carbonate cements in Chang 8 reservoir in southeastern margin of Ordos basin[J]. Lithologic Reservoirs, 2011, 23(4):65-69.
[22] ����,����,������.�����ɽ��´��ҳ��Ԫ�ص���ѧ������������������[J].�ྻú����,2012,18(1):109-112. LI Jing-jing, TAO Shu, LIU Xiao-hua. Element geochemical characteristics and implications on sedimentary environments of southern Bogda Mountain oil shale[J]. Clean Coal Technology, 2012,18(1):109-112.
[23] �罨��,������,����,��.��³�����ݶ���ϵ��Դ�ҵ���ѧ����������Ĺ�ϵ[J].�й�����,2004,31(4):424-430. MIAO Jian-yu, ZHOU Li-fa, DENG Kun, et al. Relationship between the depositional environment and geochemistry of Permian hydrocarbon source rocks in the Turpan depression[J]. Geology in China,2004, 31(4):424-430.
[24] ����,������,�ܴ��t,��.������-ǭ�м����ܱߵ����������Դ��Ԫ�ص���ѧ��������������[J].���������������,2009,36(2):397-403. TAO Shu, TANG Da-zhen, ZHOU Chuan-yi, et al. Element geochemical characteristics of the lower assemblage hydrocarbon source rocks in southeast Sichuan-central Guizhou (Chuandongnan-Qianzhong) region and its periphery areas and their implications to sedimentary environments[J]. Geology in China, 2009, 36(2):397-403.
[25] ����,�ܶ���.΢��Ԫ�ط������б���������е�Ӧ��:�Խ������DZ����Ϊ��[J].ʯ��ʵ�����,2007,29(3):307-314. LIU Gang, ZHOU Dong-sheng. Application of microelements analysis in identifying sedimentary environment-taking Qianjiang Formation in the Jianghan basin as an example[J]. Petroleum Geology & experiment, 2007,29(3):307-314.
[26] �罨��,�Խ���,������,��.������˹��ض���ϵ��Դ�ҵ���ѧ��������������Ĺ�ϵ[J].�й�����,2007,34(3):430-435. MIAO Jian-yu, ZHAO Jian-she, LIU Chi-yang, et al. Relationship between the geochemical characteristics and sedimentary environment of Permian hydrocarbon source rocks in the Ordos basin[J]. Geology in China, 2007, 34(3):430-435.
[27] �κ�,����Ƽ,������.�ͳ�����-����ϵ̼������΢��Ԫ�ؼ���������[J].�½�ʯ�͵���,2004,25(6):631-633. HE Hong, PENG Su-ping, SHAO Long-yi. Trace elements and sedimentary settings of Cambrian-Ordovician carbonates in Bachu area, Tarim Basin[J]. Xinjiang Petroleum Geology, 2004, 25(6):631-633.
[28] Hatch J R, Leventhal J S. Relationship between inferred redox potential of the depositional environment and geochemistry of the Upper Pennsylvanian (Missourian) stark shale member of the Dennis Limestone, Wabaunsee County, Kansas, USA[J]. Chemical Geology, 1992, 99(1/3):65-82
[29] �ڸ��.����ز�Ԫ�ء�̼ͬλ�طֲ��������������Դ�ҷ�����ϵ:�Զ�����˹���Ϊ��:��ʿѧλ����[D].����:�й���ѧԺ, 2004. Tennger. The distribution of elements, carbon and oxygen isotopes on marine strata and environmental correlation between them and hydrocarbon source rocks formation:an example from Ordovician Basin, China:doctor's degree thesis[D]. Beijing:Chinese Academy of Sciences, 2004.
[30] �����,��ٻ��,Ѧ�ָ�.�ձ������-�����纣����Դ�ҷ������ɼ�������[J].�������,2014,33(1):178-189. LI Hao-yue, LIU Qian-ru, XUE Lin-fu. Development and significance of Mesozoic-Paleozoic marine hydrocarbon source rocks in Subei Basin[J]. Global Geology, 2014, 33(1):178-189.
[31] ����,��ʯ,���о�,��. �ɹ���ľ���������ϰ�����Դ��������DZ������[J].�������,2012,31(1):148-154. HUANG Long, FANG Shi, LIU Zhao-jun, et al. Characteristics of source rocks and their potential evaluation in Ta'nan sag of Tamtsag Basin, Mongolia[J]. Global Geology, 2012, 31(1):148-154.
[32] �ν�,��ʡ��,�µdz�,��.���ɹ�����������켰���������Ͱ�ɫ����΢��Ԫ�غ�ϡ��Ԫ�ص���ѧ����[J].����ѧ��,2012,86(11):1773-1780. SONG Jian, ZHAO Xing-min, CHEN Deng-chao, et al. Rare earth and trace elements geochemical characteristics of the dark Permian mudstones in Ejinaqi and its surrounding areas, western Inner Mongolia[J]. Acta Geologica Sinica, 2012, 86(11):1773-1780.
[33] ��ƽ.΢��Ԫ����������̽�е�Ӧ��[J].ʯ�Ϳ�̽�뿪��,1993,20(1):27-32. DENG Ping. The application of trace amount of elements in the exploration of oil and gas[J]. Petroleum Exploration and Development, 1993, 20(1):27-32.
[34] �ڸ��. �й�������Դ���о���չ�����ٵ���ս[J].��Ȼ����ҵ,2011,31(1):20-25. Tengger. Progress and challenges in the research of marine hydrocarbon source rocks[J]. Nature Gas Industry, 2011, 31(1):20-25.
[35] �ڸ��,���Ļ�,������,��.��������л��ʵ�̼ͬλ�ؼ�¼���价������:�Զ�����˹���Ϊ��[J].ʯ�Ϳ�̽�뿪��,2004,31(5):11-16. Tengger, LIU Wen-hui, XU Yong-chang, et al. Organic carbon isotope record in marine sediment and its environmental significance:an example from Ordos Basin, NW China[J]. Petroleum Exploration and Development, 2004, 31(5):11-16.
[36] �ڸ��,���Ļ�,������,��.�޻�����ѧ��������Ч��Դ�ҷ�������������о�[J].�����ѧ��չ,2004,20(2):193-200. Tengger, LIU Wen-hui, XU Yong-chang, et al. Correlative study on parameters of inorganic geochemistry and hydrocarbon source rocks formative environment[J]. Advances in Earth Science, 2004, 20(2):193-200.
[37] �ڸ��,���Ļ�,������,��. ���ݻ�����̼������Դ�ҵ���ѧ�ۺ���ʶ:�Զ�����˹���Ϊ��[J]. �й���ѧ(D��),2006,36(2):167-176. Tengger, LIU Wen-hui, XU Yong-chang, et al. Geochemical synthesis of highly evolved marine carbonate source rocks:an example from Ordos Basin[J]. Science in China(Ser. D), 2006, 36(2):167-176.

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1�� ������, ������, �µǻ�, ������, �س���, ��ѩ��, ������.����ɭ��ͼ���������������������������������[J]. �������, 2009,28(4): 445-450
2�� ���޾�, �ű���, ����ε, ��Ӧ��.����ɽ�������������ϵ���������ݻ�[J]. �������, 2010,29(4): 561-568
3�� ��ϲ��, Ҷ˼Դ, ���پ�, �Թ���.�ƺ�������ZK1 �����Ļ�������������ּ�������������[J]. �������, 2010,29(4): 575-581
4���Ž�ΰ,������, Ԭ�����������ᣬ�����ǣ����ң��ܳ���.̩ɽ���µ��ļͳ�����ʯӢɰ������������������ָʾ[J]. �������, 2011,30(3): 463-468
5�� ����־, ��豬B, �⾰��, ³����, ��Ԫǿ.�Ϻ��ϡ���½Ե����������������������[J]. �������, 2011,30(4): 567-572
6�� ��άƽ, �����, ����, ������.ɽ������ɽ������ͭ����ʯ����ѧ����[J]. �������, 2013,32(2): 212-220
7�� ����1, Ѧ�ָ�1, ����Ӣ2, �Դ���3, ���IJ�1.�Ϻ�����������--�������������������ݻ�[J]. �������, 2013,32(2): 359-365
8�� ������, ����, ����, ������, �.���ɹŰ���ɽ—��ӵ���½����ʯȦ��������о� —���ļͼ���������������Ҳ�°���е�б��ʯ΢��Ԫ��֤��[J]. �������, 2014,33(1): 1-10
9�� �����, ���º�, ����, ��ϣ��, ������.������ʯ����ʯ̿��¹Ȧ�����������[J]. �������, 2014,33(1): 86-93
10�� �ڽ�, ��Ρ, ���ٻ�, �ֱ�.�ĺӵ�������������������ָ������������[J]. �������, 2015,34(1): 113-119
11�� ��Զܰ, ���ʤ, ���н�, �Ž���, ������, ����, ����, �.�ຣ�����ָ��յ���ȸĪ����������������������[J]. �������, 2015,34(2): 436-444
12�� ���, ������, ������, ������, ������, ����.ɽ���߱�ɽ��ͭ���������������΢��Ԫ�����������������[J]. �������, 2015,34(3): 656-663
13�� ��˷, ���о�, ��ƽ��, ������, л��Ȫ, ������.��ɫ���Ҳ�ϵ����ѧ��������Դ����—��������ض���¡�����ϰ���ͳҦ����Ϊ��[J]. �������, 2015,34(3): 774-785
14�� �¾�ʤ, �ϵº�, ���, �ŵ¾�, �����, �����, ��־��.���ɹ�Ԫ��ɽС����Ӫ�ӵ������澮���������[J]. �������, 2015,34(4): 1013-1023
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