[an error occurred while processing this directive] ������� 2010, 29(4) 668-682 DOI:     ISSN: 1004-5589 CN: 22-1111/P

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PubMed
Article by Ji, G. J. 1
Article by Li, X. J. 2
Article by Hao, L. 2
Article by Li, G. H. 1
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1. ���ִ�ѧ��ѧѧԺ������130026; 2. ���������������ι�˾������������163453
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���ø�������ҳ�һ�����ʪ����ȡ��������Ϊ������ϻ��ʣ������ø��¹��෨�ϳ� CaAl2O4 : Eu3 + ��R + ( R = Li��Na��K��Rb) ӫ��ۡ���Ѻϳ�����Ϊ: �ս��¶�1 200 �棬�ս�ʱ��3 h�����ۼ�������3 wt%�������������3 mol%; ʵ�鷢�ָ�����������ΪLi + ʱ��CaAl2O4 : Eu3 + �� Li + �ķ���ǿ����ǿ����Ʒӫ����׷���������������������615 nm ������ǿ�׷壬����ΪEu3 + ��5D0→7F2 ԾǨ���䡣

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Aluminate luminescence material preparation with alumina extracted by oil shale ash
JI Gui-Juan-1, LI Xiao-Jun-2, HAO Lei-2, LI Guang-Huan-1
1. Department of Chemistry��Jilin University��Changchun 130026��China; 2. Daqing Oilfield Limited Company��Daqing 163453��Heilongjiang��China
Abstract:

CaAl2O4 : Eu3+ ��R + ( R = Li��Na��K��Rb) phosphor powder was prepared by high temperature solid-state method��in which Alumina has been extracted in wet-process as the substrate of luminescent materials used dry distillated oil shale ash��The optimal synthetic conditions are sintering temperature and time are 1 200 �� by 3 h��the concentration of fluxing agent and activated ion ratio are 3 wt% and 3 mol%��respectively�� The experiment indicated when auxiliary activated ion is Li+ ��the luminescent intensity of CaAl2O4 : Eu3+ ��Li+ is the strongest��The analysis of fluorescence spectrum showed that the emission spectrum exhibited a sharp peak at 615 nm�� ascribed to 5D0→7F2 transition of Eu3+ ��

Keywords: red luminescent powder   aluminate   spectral characteristics   oil shale ash  
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