[an error occurred while processing this directive] ������� 2010, 29(1) 168-174 DOI:     ISSN: 1004-5589 CN: 22-1111/P

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PubMed
Article by Ji, P.
Article by She, Z. B.
Article by Li, X. H.
Article by Liu, J.
Article by Zhang, M.
Article by Zhang, K.
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����2-������ż����-1, 8-���ǻ�-3, 6-��������(���Լ�) ��Ϊ���ϼ��Ʊ������γ���֬, ���о��˸���֬�����ܼ��Է��븻���Ͳⶨ�����Ӱ�����ء�ʵ�鷢��, ��pH = 1.0��������Һ����ϴ��������Ϊ8 cm������Ϊ1.00 mL /min��pH = 1.0��3%������-����40 mLϴ��ʱ, ����������ܺͳ����Ľ������ӷ���, ������������֬�ϡ��ü��׷��ⶨ�����Ԫ�صı�׼����ʵ�����, �������Ϊ94% ��106%��

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Noble metal elements of oscillopolarography samples after separation and enr ichment by arsenazo chelate-forming resin
JI Peng, SHE Zhen-Bao, LI Xian-Hong, LIU Jing, ZHANG Min, ZHANG Kai
College of Chemistry, Jilin University, Changchun 130026, China
Abstract:

Used 2-o-arsenic acid, phenylazo-1, 8-dihydroxy-3, 6-2 disulfonate ( arsenazo) as chelating agent to prepare chelate-forming resin, the properties of the resin and influence factors of separation and enrichment and measurement results have been studied. The experiments show that taking hydrochloric acid as eluentwith pH 1.0, height of column 8 cm and the velocity of flow 1.00 mL /min, the noble metal ions can be separated from common metallic ions when eluted by 40 mL thiourea-hydrochloric acid with pH 1.0 and concentration 3%, and concentrated on the resin quantificationally. The ratio of noble metal elementsprecovery in the standard recovery experiment is 94%��106% by oscillopolarography.

Keywords: arsenazo   chelate-forming resin   separation and enrichment   oscillopolarography   noble metal element  
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